Eu³⁺/Tb³⁺-codoped Y₂O₃ nanophosphors: Rietveld refinement, bandgap and photoluminescence optimization

Abstract

Abstract In this work, Eu-doped, Tb-doped and Eu, Tb-codoped Y 2 O 3 nanophosphors were synthesized by the combustion synthesis method. The prepared phosphors were characterized by x-ray diffraction (XRD), Rietveld refinement and Fourier transform infrared (FTIR) spectroscopy. XRD studies and Rietveld refinement confirmed the body-centred cubic structure of doped and codoped phosphors. FTIR studies also confirmed the formation of these compounds. Thermal analysis results indicated that there was no phase transition for all the phosphors in the studied temperature range. In the optical properties, diffuse reflectance (DR) and photoluminescence (PL) measurements were performed. DR spectra were used to determine the bandgap and it increased in the doped and codoped samples due to the crystallite size effect. A strong characteristic emission from Eu 3+ and Tb 3+ ions was identified and the influence of doping concentration and annealing temperature on PL properties was systematically studied. Transfer of energy was observed from Tb 3+ to Eu 3+ ions in the codoped phosphor at room temperature.