Journal of Physics C Solid State Physics · 1986 · 12 citations · 6 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMaterials ThermodynamicsThermodynamicsPhase EquilibriaPhase RelationsPhase TransitionsThermal Properties Of CeramicsThermal Properties Of MaterialsThermodynamics Of CeramicsHeat CapacityHeat Capacity DeterminationThermodynamic AnalysisThermodynamic ForcesThermodynamics Of Ionic SolidsUnit Cell DeterminationUnit Cell ParametersUnit Cell Volume
The temperature dependences of the heat capacity for Cs2NaNdCl6 and of the unit cell parameters for Cs2NaNdCl6 and Cs2NaPrCl6 have been investigated over a wide temperature range including the temperature at which the phase transition Oh5-C4h5 occurs. Analysis of the results has been performed in terms of thermodynamic theory. The coefficients of the thermodynamic potential expansion and the values of the tilt angles of B3+Cl6 octahedra have been determined.
6