Satellite band structure in silicon caused by electron-plasmon coupling

Abstract

We report an angle-resolved photoemission measurement of the wave-vector-dependent plasmon satellite structure of a three-dimensional solid, crystalline silicon. In sharp contrast to nanomaterials, which typically exhibit strongly wave-vector-dependent low-energy plasmons, the large plasmon energy of silicon facilitates the search for a plasmaron state consisting of resonantly bound holes and plasmons and its distinction from a weakly interacting plasmon-hole pair. Employing a first-principles theory, which is based on a cumulant expansion of the one-electron Green's function and contains significant electron correlation effects, we obtain good agreement with the measured photoemission spectrum for the wave-vector-dependent dispersion of the satellite feature, but without observing the existence of plasmarons in the calculations.