Étude de la solvatation préférentielle des poly(méthacrylates de méthyle) dans quelques mélanges de solvants

Abstract

Abstract The behavior of some poly(methyl methacrylate)s in solvent‐mixtures (benzene‐methanol, carbone tetrachloride‐methanol and dioxane‐methanol) was investigated. The dependence of microstructure and molecular weight of the polymer on the preferential solvation was determined. The existence of a conformational transition for syndiotactic poly(methyl methacrylate) in dioxane and in dioxane‐methanol could be shown.