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A Facile Synthesis of α, α'-bis(Substituted Benzylidene)cycloalkanones Catalyzed by bis(<i>p</i>-ethoxyphenyl)telluroxide(bmpto) Under Microwave Irradiation
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Citations
3
References
1997
Year
Chemical EngineeringCross-coupling ReactionEngineeringHeterocyclicFacile SynthesisOrganic ChemistryMicrowave IrradiationCatalysisHigh YieldChemistryMicrowave SynthesisSynthetic ChemistryEnantioselective SynthesisSubstituted Benzylidene
Abstract The bis(4-methoxyphenyl)telluroxide(BMPTO) catalyzed reaction of cyclopentanone or cyclohexanone with aldehydes brought about the cross-aldol condensation to give the corresponding 2, 5-bis(substituted benzylidene) cyclopentanones or 2, 6-bis(substituted benzylidene)cyclohexanones in high yield under microwave irradiation in mild conditions. The reaction needs only 5-10 min.
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