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A definite evidence on the ambivalent azomethine ylide intermediate in trifluoroacetic acid- and fluoride anion-promoted 1,3-cycloadditions involving the silicon-carbon bond cleavage.
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1985
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Inorganic ChemistryEngineeringHeterocyclicSilicon-carbon Bond CleavageDefinite EvidenceFluorous SynthesisOrganic ChemistryAnion-promoted 1Trifluoroacetic Acid-ChemistryFluoride Anion-promoted 1,3-CycloadditionsSynthetic ChemistryBiomolecular EngineeringInorganic Compound
Trifluoroacetic acid- and fluoride anion-promoted 1, 3-cycloadditions of N-benzyl-N-(methoxymethyl) trimethylsilylmethylamine to dipolarophiles were found to proceed via the ambivalent azomethine ylide intermediates.