Publication | Closed Access
The Valence Structure of the Boron Hydrides
240
Citations
12
References
1954
Year
EngineeringComputational ChemistryChemistryElectronic StructureBoropheneBoron NitrideValence StructureExtended Valence PostulatesInorganic ChemistryPhysicsChemical BondAtomic PhysicsHydrogenQuantum ChemistryLocalized Three-center BondNatural SciencesCondensed Matter PhysicsApplied PhysicsHydrogen BondBoron Hydrides
A set of extended valence postulates is presented including the concept of the localized three-center bond. These postulates are applied systematically to the boron hydrides and account for their unusual geometry, their unexpected dipole moments, and the fact that they are not ``electron-deficient.''
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