Polyoxometalates covalently bonded with terpyridine ligandsElectronic supplementary information (ESI) available: experimental. See http://www.rsc.org/suppdata/cc/b3/b307415c/

Abstract

A terpyridine ligand is covalently linked to a hexamolybdate cluster through the Mo-N imido bond, paving the way for the preparation of hybrids containing covalently bonded transition metal complexes and polyoxometalate clusters.