Die Makromolekulare Chemie · 1984 · 26 citations · 15 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryPolymer ChemistryPolymer MaterialsPolymer CharacterizationPolymer CrystallinityPolymer Physical ChemistryPolymer PhysicsPolymer StructureIntercalation PolymersPolyacetylenePolymer Crystal Structure
Abstract The doping of deuterated polyacetylene ( cis and trans ) with AsF 5 was studied by neutron diffractometry. A method of optimize the crystallinity of the doped material is described. Evidence for the presence of two species in the doped polymer which are probably AsF 6 − and AsF 3 is presented. Model calculations based on a series of [CD x H 1‐x (AsF 5 ) y ] n samples support a “first‐stage” intercalation structure with a graphitic structure.
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The chemical nature of polyacetylene doping
Thomas C. Clarke, G. B. Street · Synthetic Metals · 1980 · 50 citations
Absence of Knight-shift in the metallic state of polyacetylene
M. Peo, H. Förster, Klaus Menke et al. · Solid State Communications · 1981 · 42 citations