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P2-Ligand Complexes as Building Blocks for the Formation of One-Dimensional Polymers This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.
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2002
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One-dimensional PolymerBuilding BlocksEngineeringP2-ligand ComplexesChemistryPolymersChemical EngineeringPolymer ChemistryMaterials ScienceInorganic ChemistryMo2p2 ComplexesOne-dimensional PolymersOrganometallic PolymerCoordination ComplexSelf-assemblyPolymer ScienceMolecular ComplexCoordination PolymerZigzag Polymer ChainInorganic Polymer
Bridging coordination of Mo2P2 complexes between metal centers is a prerequisite for the formation of a one-dimensional polymer. The choice of counterion also has a deciding role in determining the polymer structure: while the complex [Cp2Mo2(CO)4(μ,η2-P2)] (1; Cp=C5H5) with AgNO3 forms a zigzag polymer chain, with CuBr 1 forms a linear coordination polymer (see structure).