Die Makromolekulare Chemie · 1958 · 40 citations · 4 references
Natural SciencesChemistryPolymer ChemistryPolymer EngineeringPolymer MaterialsPolymer Physical ChemistryPolymer SynthesisPolymerization ChemistryPolymerization KineticsPolymerization ProcessesPolymerization Temperature EffectsActivation EnergyPolymer InitiatorsPolymerization ThermodynamicsTemperature Dependence Of PolymerizationThermal Activation Of PolymerizationThermal PolymerizationVinyl PolymerizationVinyl Polymers
Abstract A study of the polymerization of styrene initiated by various tetralkyl thiuram disulfides has been made at the temperature range from 50 to 90°C. It was proved that the rate of polymerization increased with the 0.3–0.5 power of the Concentration of thiuram initiator and showed an over‐all activation energy of 17 to 23 Kcal./mole. These thiuram disulfides had a retarding action on the polymerization of styrene and weak initiating Activity under thermal conditions. However; in the presence of Eght, they were excellent as polymerization initiators.
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