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Reaktion von Tetraschwefeltetranitrid mit Rhenium(VII)-chloronitrid Die Kristallstruktur von [Ph<sub>4</sub>As<sup>+</sup> ]<sub>2</sub> [Cl<sub>4</sub> Re(NS)(NSCl) <sup>2-</sup> ] · CH<sub>2</sub> Cl<sub>2</sub> / Reaction of Tetrasulfurtetranitride with Rhenium(VII)-chloronitride The Crystal Structure of [Ph<sub>4</sub> As<sup>+</sup> ]<sub>2</sub> [Cl<sub>4</sub> Re(NS)(NSCl)<sup>2-</sup> ] · CH<sub>2</sub>Cl<sub>2</sub>
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1985
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Inorganic ChemistryChemical EngineeringPh 4EngineeringCrystal StructureCoordination ComplexCl 4Cl 10Main Group ChemistryChemistrySynthetic ChemistryInorganic SynthesisInorganic Compound
Abstract The synthesis of [Ph 4 As + ] 2 [Cl 4 Re(NS)(NSCl) 2- ] · CH 2 Cl 2 (4) from the reaction of S 4 N 4 , Cl 4 ReN, and Ph 4 AsCl is reported. CH 2 Cl 2 is used as solvent. The reaction of S 4 N 4 with Re 2 Cl 10 similarly leads to the salt [Ph 4 As + ][Cl 2 ReNS - ] (5) in a smaller yield. 4 crystallizes in the triclinic space group P1̅ with Z = 2, a - 10.434(2), b = 12.1454(6), c = 21.125(2) Å, a = 81.210(6), β = 86.70(1), γ = 76.624(8)°.