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A method for synthesizing the diformylcyclopentene moiety of halimedatrial.
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1989
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Diformylcyclopentene Moiety 2__-EngineeringHeterocyclicAlkene MetathesisActive FormOrganic ChemistryStereoselective SynthesisChemistryHeterocycle ChemistryDiformylcyclopentene MoietySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
The diformylcyclopentene moiety 2__- of halimedatrial was stereoselectively synthesized in an optically active form from (S)-4-hydroxy-2-cyclopentenone (3__-) via 4-alkyl-2-cyclopentenone 6__- and cyclobutene 8__-.