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Synthesis of a New Cerebroside from a Chondropsis sp. Sponge.
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1991
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Tissue EngineeringAbsolute StructureBioorganic ChemistryEngineeringBiochemistryNatural SciencesGlycobiologyChondropsis SpOrganic ChemistryNew Cerebroside 1BPolysaccharideStereoselective SynthesisChemistryNatural Product SynthesisSynthetic ChemistryEnantioselective Synthesis
A cerebroside, 1-O-(β-D-galactopyranosyloxy)-(2S, 3S, 4R, 6E)-2-[(R)-2-hydroxytetracosanoylamino]-17-methyl-6-octadecene-3, 4-diol (2), was asymmetrically synthesized from isobutyraldehyde. On the basis of a comparison of the physical data, the absolute structure of a new cerebroside 1b from a Chondropsis sp. sponge is thought to be the same at that of 2.