A General, Practical Palladium‐Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides

Abstract

Mit der ungiftigen Cyanidquelle K4[Fe(CN)6]⋅3 H2O gelingt die Cyanierung von (Hetero-)Arylhalogeniden. Durch Einsatz von Palladacyclen werden Vergiftungsprozesse bei der Bildung des Katalysators vermieden. Die Vorteile sind geringe Katalysatormengen, kurze Reaktionsdauer und ein weites Heterocyclen-Substratspektrum. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.