Destruction of Chlorodifluoromethane $(\hbox{CHF}_{2} \hbox{Cl})$ by Using Dielectric Barrier Discharge Plasma

Abstract

The destruction of chlorodifluoromethane (CHF <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cl) was studied in a nonthermal atmospheric pressure plasma reactor with a perforated dielectric barrier, which is capable of producing intense streamers without significant pressure drop across the reactor. The performance of the dielectric barrier discharge reactor was evaluated with the parameters including oxygen content, input power, feed-gas flow rate, and initial CHF <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cl concentration. It was found that the reactive species from N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> mainly contributed to the destruction of CHF <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cl rather than those from oxygen and that the destruction efficiency largely decreased as the oxygen content increased. The change in the initial concentration did not nearly affect the destruction efficiency, which can partly be explained by the secondary destruction mechanism. The principle byproducts were identified using Fourier transform infrared spectroscopy, and chemical mechanisms were proposed for the destruction processes. According to the proposed mechanisms, COF <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> was found to act as the key intermediate destruction product to convert CHF <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cl into CO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> and CO.