Origin of apparent colossal dielectric constants

Abstract

Experimental evidence is provided that colossal dielectric constants ${\ensuremath{\varepsilon}}^{\ensuremath{'}}>~1000,$ sometimes reported to exist in a broad temperature range, can often be explained by Maxwell-Wagner-type contributions of depletion layers at the interface between sample and contacts or at grain boundaries. We demonstrate this on a variety of different materials. We speculate that the largest intrinsic dielectric constant observed so far in nonferroelectric materials is of order ${10}^{2}.$