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β<sub>LG</sub> values in mechanistic studies on the transesterification of RNA models and their application in a metal ion complex promoted transesterification
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2012
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Mechanistic StudiesEngineeringMolecular BiologyOrganic ChemistryChemistryNucleic Acid ChemistryRna ModelsMini ReviewOrganometallic CatalysisRna ProcessingBiochemistryRna BiologyCatalysisMetal Ion ComplexNatural SciencesEnzyme CatalysisNucleic Acid BiochemistryBiotechnologyβ Lg ValuesTransesterification Reactions
Studies on the mechanism of transesterification reactions of nucleoside 3′‐phosphoesters using β LG values as a mechanistic tool are discussed in this mini review. Our recent observation that a dinuclear metal ion complex enhances both the cleavage and isomerisation is discussed in the light of previous studies. Copyright © 2012 John Wiley & Sons, Ltd.
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