Physical Review Letters · 2008 · 88 citations · 15 references
Natural SciencesPhysicsHeat TransferStochastic ProcessesThermodynamicsDissipative SystemsEntropyMarkov ProcessesNon-equilibrium ThermodynamicsStatistical MechanicsStatistical ThermodynamicsEntropy ChangeFluctuation TheoremsFluctuation TheoryNon-equilibrium Statistical MechanicsNonequilibrium Steady StatesStationary StatesStatistical Foundations Of ThermodynamicsThermodynamic Forces
We study the nonequilibrium steady state realized in a general stochastic system attached to multiple heat baths. Starting from the detailed fluctuation theorem, we derive concise and suggestive expressions for the corresponding stationary distribution which are correct up to the second order in thermodynamic forces. The probability of a microstate $\ensuremath{\eta}$ is proportional to $\mathrm{exp}[\ensuremath{\Phi}(\ensuremath{\eta})]$ where $\ensuremath{\Phi}(\ensuremath{\eta})=\ensuremath{-}\ensuremath{\sum}_{k}{\ensuremath{\beta}}_{k}{\mathcal{E}}_{k}(\ensuremath{\eta})$ is the excess entropy change. Here, ${\mathcal{E}}_{k}(\ensuremath{\eta})$ is the difference between two kinds of conditioned path ensemble averages of excess heat transfer from the $k$th heat bath whose inverse temperature is ${\ensuremath{\beta}}_{k}$. This result can be easily extended to steady states maintained with other sources, e.g., particle current driven by an external force. Our expression may be verified experimentally in nonequilibrium states realized, for example, in mesoscopic systems.
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Fluctuations and Irreversible Processes
Lars Onsager, Stefan Machlup · Physical Review · 1953 · 1.8K citations
Fluctuation theorem for stochastic dynamics
Jorge Kurchan · Journal of Physics A Mathematical and General · 1998 · 1.1K citations · Full text