Disposal of reverse osmosis concentrate (ROC) from advanced water purification facilities is a challenge associated with the implementation of reverse osmosis-based treatment of municipal wastewater effluent for potable reuse. In particular, the dissolved organic matter (DOM) present in ROC diminishes the quality of the receiving water upon environmental disposal and affects the toxicity, fate, and transport of organic contaminants. This study investigates UV-based advanced oxidation processes (UV-AOPs) for treating DOM in ROC using a Parallel Factor Analysis (PARAFAC) approach. DOM composition and degradation were tested in UV-only and three UV-AOPs using hydrogen peroxide (H₂O₂), free chlorine (Cl₂), and persulfate (S₂O₈^2-). The four-component PARAFAC model consisted of two terrestrial humic-like components (C_UVH and C_VisH), a wastewater/nutrient tracer component (C_NuTr), and a protein-like (tyrosine-like) component (C_PrTy). Based on the observed loss in the maximum fluorescence intensity of the components, DOM degradation was determined to be dependent on UV fluence, oxidant dose, and dilution factor of the ROC (i.e., bulk DOM concentration). C_VisH was most the photolabile component in the UV-only system, followed by C_NuTr, C_PrTy, and C_UVH, respectively. Furthermore, UV-H₂O₂ and UV-S₂O₈^2- displayed faster overall reaction kinetics compared to UV-Cl₂. The degradation trends suggested that C_NuTr and C_PrTy consisted of chemical moieties that were susceptible to reactive oxygen species (HO^•) but not reactive chlorine species; whereas, C_VisH was sensitive to all reactive species generated in the three UV-AOPs. Compared to other components, C_PrTy was recalcitrant in all treatment scenarios tested. Calculations using chemical probe-based analysis also confirmed these trends in the reactivity of DOM components. The outcomes of this study form a foundation for characterizing ROC reactivity in UV-AOP treatment technologies, to ultimately improve the sustainability of water reuse systems.

	Year	Citations

About