Graphitic carbon nitride modified by molybdenum trioxide (g-C₃N_4/MoO₃) as a nanohybrid was synthesized by co-precipitation method. Here, g-C₃N₄/MoO₃ nanohybrid was used for the first time as an adsorbent for the pharmaceutical drug, diclofenac, (an aqueous micropollutant) from water to mitigate its possible environmental toxic effects. Compared to pristine components, the nanohybrid exhibited better adsorptive removal of diclofenac. Adsorption was enhanced with increment in MoO₃ content from 1 to 3 wt %; however further increment in MoO₃ content resulted in lower adsorption capacity due to agglomeration of MoO₃ particles over g-C₃N₄. 162 mg g^-1 adsorption capacity was achieved for 300 mg L^-1 diclofenac in solution with 1 g L^-1 adsorbent at pH = 6. Adsorption of diclofenac over g-C₃N₄ /MoO₃ followed pseudo 2nd order kinetics. Temkin, Langmuir, Dubinin Radushkevich and Freundlich isotherm models were applied on the experimental results concluding that diclofenac adsorption over g-C₃N₄/MoO₃ followed the Langmuir isotherm. The adsorption mechanism could be explained by the π-π interaction between aromatic rings of diclofenac and g-C₃N₄/MoO₃ (3%) nanohybrid, which is also evident by the FTIR results. This study presents the facile fabrication of a 2nd generation adsorbent for the treatment of diclofenac contaminated water that may as well help achieve the removal of other micropollutants form water.

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