21:T41f,Aqueous lead sulfide (PbS) quantum dots (QDs) synthesized by traditional methods are unstable, so that they are usually coated with cadmium sulfide (CdS) to prevent oxidation, which are complicated and not satisfactory for mass production. Here, stable ternary Pb_1-x Cd_x S QDs were synthesized by in situ coprecipitation of Pb_4-n Cd_n O₄ bimetallic clusters in an aqueous solution, which possess a uniform size of 4.0±0.2 nm and the second near-infrared (NIR-II) emission at 1100 nm with photoluminescence quantum yield (PLQY) as high as 17.72 %. Stored at 4 °C and in colloidal form, the PLQY of Pb_1-x Cd_x S QDs remained at 90.9 % of the initial value after 15 days, while stored as powder, the spectra did not change after 5 months. The high PLQY and good water compatibility of Pb_1-x Cd_x S QDs provide a good performance in vivo vasculature imaging and lymphatic system imaging at a very low power density (10 mW cm^-2 ) in the NIR-II window.22:T40d,Constructing a solid electrolyte interface (SEI) layer to suppress dendrite growth is an effective approach in Zn-based aqueous batteries. Traditional SEI layers are limited by their simple structure and composition, enabling only one functionality of either providing nucleation sites or facilitating desolvation. In this study, a pulse guidance ion-accelerator is constructed by kinetics-controlled co-assembly of zincophilic micelles and zincophobic metal-organic framework (MOF). The closely packed soft micelles, in conjunction with the hard MOF host particles, form a multi-tiered soft-in-hard hetero-structure that accelerates adsorption, pre-desolvation, and subsequent desolvation processes, facilitating the (002) crystal plane dendrite-free deposition. As a result, stable cycling over 1900 h (31 mV polarization) in symmetric cell and 5200 cycles in the Zn//Cu battery (99.8% coulombic efficiency) can be achieved. These findings will effectively promote the development of stable and long-cycling aqueous zinc-ion batteries.

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