21:I[432972,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 22:T523,Developing safe and efficient diclofenac sodium (DS) removal technology has become a critical issue. This study synthesized the fish-scale biochar by co-pyrolysis of fish scale and phosphoric acid (H₃PO₄). In addition to increasing the specific surface area and pore volume of fish-scale biochar, H₃PO₄ assisted in the formation of Graphitic N and sp² C, as well as reacting with C═O groups to form a significant number of phosphorus-containing groups. All these functional groups could act as major active sites for DS adsorption. Adsorption data could well fit pseudo-second-order and Langmuir models. The maximum adsorption capacity of FSB_600-15 for DS was 967.1 mg g^-1, which was much better than that reported in the literature. Under the synergistic effect of various mechanisms (pore-filling effect, electrostatic attraction, H-bonding, π-π, and n-π electron donor-acceptor interactions), the DS ultra-efficient adsorption on FSB_600-15 was realized. Meanwhile, the DS adsorption by FSB_600-15 was an endothermic, spontaneous, and entropy-increasing process. Furthermore, the DS adsorption capacity was more than 426.5 mg g^-1 in the actual water, which was sufficient for practical applications.

#	Concept	H-Index	Publications	Citations
1	Engineering	1	1	45
2	Chemical Engineering	1	1	45
3	Chemistry	1	1	45
4	Biochemical Engineering	1	1	45
5	Biochar	1	1	45

	Year	Citations

About

Top Concepts