1b:I[76749,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 1c:I[3486,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 1d:I[41892,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 1e:I[17707,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 1f:I[66528,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 20:I[63176,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 21:I[87099,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 22:I[26200,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"Group"] 23:I[23365,["/_next/static/chunks/f9f65a69b09cd00d.js","/_next/static/chunks/1ba21a8e081e29d1.js","/_next/static/chunks/0383663887945ae7.js","/_next/static/chunks/5bf36002c846d2d8.js","/_next/static/chunks/63561dcd578bd4db.js","/_next/static/chunks/29d2646804fd1cab.js","/_next/static/chunks/2060b26370dc6c0a.js"],"default"] 24:T47c,The synthesis, and spectroscopic and structural characterization of bridged dicationic derivatives of benzo-2,1,3-selenadiazoles are reported. The chloride salt of [H₄C₆NSeN-CH₂-CH₂-NSeNC₆H₄]²⁺ crystallizes forming a macrocyclic structure in which two cations are bridged by SeCl chalcogen bonds (ChBs), with a third chloride at the centre of the macrocycle. The structure of [1,2-(H₄C₆NSeN)₂-C₆H₁₀]Cl₂ consists of two selenadiazolium cations linked by a chiral cyclohexane and capped by SeCl ChBs. Tetrafluoroborate salts of a xylene bridge crystallize in two pseudopolymorphs in which the cations form SeF ChBs in an anti- or syn-conformation. The triflate salt of ethylene-bridged cations dimerizes through the formation of the [Se-N]₂ supramolecular synthon with SeO ChBs capping the second selenium atom. In contrast, [H₄C₆NSeN-CH₂-CH₂-CH₂-NSeNC₆H₄](CF₃SO₃)₂ only forms SeO ChBs.

Faisal Adam Pani

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